Synthesis of angularly fused aromatic compounds from alkenyl enediynes by a tandem radical cyclization process |
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Authors: | Roy Snigdha Anoop Anakuthil Biradha Kumar Basak Amit |
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Affiliation: | Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302 (India). |
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Abstract: | Let's get radical: A general synthetic route toward angularly ortho-fused polyaromatic [4]helicenes starting from aryl alkenyl N-substituted cyclic enediynes is described (see scheme; DMSO=dimethyl sulfoxide, Ns=4-nitrobenzenesulfonyl). The process involved a Bergman cyclization (BC) as the key step of an unprecedented tandem radical reaction. |
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Keywords: | cyclizations density functional calculations enediyne radicals tandem reactions |
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