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Tris(thiocyanate) Ruthenium(II) Sensitizers with Functionalized Dicarboxyterpyridine for Dye-Sensitized Solar Cells
Authors:Yang Shen-Han  Wu Kuan-Lin  Chi Yun  Cheng Yi-Ming  Chou Pi-Tai
Institution:Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30013 (R.O.C.).
Abstract:Panchromatic sensitizers: A series of ruthenium(II) compounds was prepared that contain three thiocyanate ligands and a novel chelating terpyridine ligand. The latter (see picture: colors indicate orbital occupation) serves as an effective and versatile light-harvesting auxochrome. One compound has a solar conversion efficiency of up to 10.3?%.
Keywords:dye‐sensitized solar cells  N ligands  ruthenium  thiocyanate  thiophene
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