Study of the reaction of dichloromethane with hydrogen fluoride in the presence of antimony chlorofluorides |
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| Authors: | D V Vinogradov V A Khomutov |
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| Institution: | (1) Russian Scientific Research Center of Applied Chemistry, St. Petersburg, Russia |
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| Abstract: | The reaction of dichloromethane with hydrogen fluoride in the presence of antimony chlorofluorides is studied in the setup
for liquid-phase synthesis. The reaction type, orders with respect to reactants and the catalyst, and Arrhenius parameters
are determined. The elemental composition of the catalyst for liquid-phase fluorination in the considered process is found.
The dynamics of the catalyst activity is studied. |
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