Novel metalloreagent Cp(CO)2FeP(Se)(OR)2 produced from P-Se bond cleavage in the thermal reaction of [CpFe(CO)2]2 with phosphor-1,1-diselenolates |
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| Authors: | Liu C W Chen Jem-Min Santra Bidyut Kumar Wen Sung-Yin Liaw Ben-Jie Wang Ju-Chun |
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| Affiliation: | Department of Chemistry, National Dong Hwa University, Hualien 974, Taiwan. |
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| Abstract: | The reaction of [CpFe(CO)2]2 with NH4Se2P(OR)2 yields a novel reagent Cp(CO)2FeP(Se)(OR)2, which has demonstrated coordination properties at the Se center to form heterometallic clusters as well as reactivity at the Se site toward C-based electrophiles. |
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