The liquid-glass and liquid-liquid transitions of TPP at elevated pressure |
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| Authors: | Mierzwa Michał Paluch Marian Rzoska Sylwester J Zioło Jerzy |
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| Institution: | Institute of Physics, University of Silesia, Katowice, Poland. |
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| Abstract: | We studied the polyamorphism of the liquid triphenyl phosphite by means of broadband dielectric spectroscopy at ambient and elevated (p=500 MPa) pressures. The effect of pressure on fragility, liquid-liquid phase transition, and its kinetics is discussed in relation to the two-order-parameter model proposed by Tanaka. The experimental evidence in support of this model is presented. |
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