Thermotropic liquid crystalline ionic stilbazoles and their miscible mixtures with non-ionic carbazolyl compounds |
| |
Authors: | Yozo Kosaka Takashi Kato Toshiyuki Uryu |
| |
Affiliation: | a Central Research Institute, Dai Nippon Printing Co., Ltd., Tokyo, Japanb Institute of Industrial Science, University of Tokyo, Tokyo, Japan |
| |
Abstract: | New thermotropic ionic liquid crystals were prepared from trans-4-nitro-4'-stilbazole and alkyl halides. trans-N-Alkyl-4-nitro-4'-stilbazolium bromides containing alkyl chains with 7 to 10 carbons and the chloride homologues containing alkyl chains with 5 to 10 carbons exhibited smectic phases. For example, trans-N-decyl-4-nitro-4'-stilbazolium bromide and trans-N-hexyl-4-nitro-4'-stilbazolium chloride showed smectic phases from 175 to 186°C and from 129 to 190°C, respectively. The temperature range of mesophases increased with decreasing size of the counteranions. The miscibility of trans-N-alkyl-4-nitro-4'-stilbazolium bromide in Schiff's base compounds having various electronegative groups was examined by differential scanning calorimetry and polarizing microscopy. Miscible binary mixtures were prepared from trans-N-alkyl-4-nitro-4'-stilbazolium bromides and 4-alkoxy-N-(9-methyl-2-carbozolyl-methylene)anilines. The 1:1 (mole ratio) binary mixture of trans-N-hexyl-4-nitro-4'-stilbazolium bromide with 4-hexyloxy-N-(9-methyl-2-carbazolylmethylene)aniline exhibited a stable smectic phase between 83 and 149°C, though a smectic phase is not exhibited by both individual components. The miscibility in the binary mixtures might be caused by a combination of ionic and electron donor-acceptor interactions. |
| |
Keywords: | |
本文献已被 InformaWorld 等数据库收录! |
|