State of rhodium(III) in sulfuric acid solutions |
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| Authors: | A V Belyaev M A Fedotov S N Shagabutdinova |
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| Institution: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia;(2) Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia |
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| Abstract: | The formation of rhodium(III) sulfate complexes under moderately rigorous temperature conditions was studied by 103Rh and 17O NMR spectroscopy. The complexes Rh2(μ-SO4)2(H2O)8]2+, Rh2(*μ-SO4)(H2O)8]4+, and Rh3(μ-SO4)3(μ-OH)(H2O)10]2+ were found to be the most stable species in aged solutions. |
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