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Recent advances of defect-induced spin and valley polarized states in graphene
Institution:1.School of Integrated Circuits and Electronics, MIIT Key Laboratory for Low-Dimensional Quantum Structure and Devices, Beijing Institute of Technology, Beijing 100081, China;2.Advanced Research Institute of Multidisciplinary Sciences, Beijing Institute of Technology, Beijing 100081, China;3.Center for Advanced Quantum Studies, Department of Physics, Beijing Normal University, Beijing 100875, China
Abstract:Electrons in graphene have fourfold spin and valley degeneracies owing to the unique bipartite honeycomb lattice and an extremely weak spin-orbit coupling, which can support a series of broken symmetry states. Atomic-scale defects in graphene are expected to lift these degenerate degrees of freedom at the nanoscale, and hence, lead to rich quantum states, highlighting promising directions for spintronics and valleytronics. In this article, we mainly review the recent scanning tunneling microscopy (STM) advances on the spin and/or valley polarized states induced by an individual atomic-scale defect in graphene, including a single-carbon vacancy, a nitrogen-atom dopant, and a hydrogen-atom chemisorption. Lastly, we give a perspective in this field.
Keywords:graphene  atomic-scale defect  broken symmetry  spin and valley polarized states  
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