| 钪、钇硝酸盐与5-Br-PADAP固体配合物的合成及性质研究 |
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| 引用本文： | 王桂兰,胡之德.钪、钇硝酸盐与5-Br-PADAP固体配合物的合成及性质研究[J].无机化学学报,1986,2(4):106-111. |
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| 作者姓名： | 王桂兰 胡之德 |
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| 作者单位： | 兰州大学化学系
(王桂兰)，兰州大学化学系(胡之德) |
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| 摘 要： | 关于5-Br-PADAP与金属离子固态配合物的研究,迄今为止国内外未见报导。本文在丙酮中使5-Br-PADAP与硝酸钪及硝酸钇反应,制得了它们的固态配合物。分析了配合物的组成,并对其红外光谱、紫外—可见光谱、溶解性及摩尔电导、差热—热重分析、X光粉末衍射等性质进行了研究。
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| 关 键 词： | 钪 钇 苯酚 配合物 合成 |
| 收稿时间： | 1/6/1986 12:00:00 AM |
SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF SCANDIUM AND YTTRIUM NITRATES WITH 5-Br-PADAP |
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| Wang Guilan and Hu Zhide.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF SCANDIUM AND YTTRIUM NITRATES WITH 5-Br-PADAP[J].Chinese Journal of Inorganic Chemistry,1986,2(4):106-111. |
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| Authors: | Wang Guilan and Hu Zhide |
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| Abstract: | The solid complexes of scandium and yttrium nitrates with 2-(5-bromo
-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAF) have been synthesized using acetone as reaction medium. Composition of complexes were determined by elemental analysis as following:
Sc(NO3)2L.HL1/2H2O, Y(NO3)3 ?(HL)3 ?2H2O(HL = 5-Br-PADAP)
The complexes have been characterized by infrared spectra, ultraviolet-visible spectra, solubilities and molar conductances, thermogravimetric (TG) and differential thermal analyses (DTA), and X-ray powder diffraction. |
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| Keywords: | scandium yttrium phenol complex synthesis |
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