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| 由MOPIP配体构筑的两种金属配合物的合成、表征及晶体结构(英文) | |
| 引用本文： | 黄艳菊,倪 良,杜 刚,崔运成,张文莉,王 蕾,郝向荣.由MOPIP配体构筑的两种金属配合物的合成、表征及晶体结构(英文)[J].无机化学学报,2010,26(7):1269-1273. |
| 作者姓名： | 黄艳菊 倪 良 杜 刚 崔运成 张文莉 王 蕾 郝向荣 |
| 作者单位： | 1. 江苏大学化学化工学院,镇江,212013;通化师范学院化学系,通化,134002 2. 江苏大学化学化工学院,镇江,212013 3. 通化市第一中学,通化,134001 4. 吉林师范大学化学学院,四平,136000 5. 通化师范学院化学系,通化,134002 |
| 摘 要： | 采用水热法由2种不同金属盐和MOPIP(MOPIP=2-(4-methoxyphenyl)-1H-imidazo4,5-f]1,10]phenanthroline)配体合成了2种新型零维配合物Cd(MOPIP)3(H2O)9]4n(1)和Mn(MOPIP)3(H2O)6]2n(2),并对其进行了元素分析、红外光谱表征、热失重和X射线单晶衍射测定。结果表明,每个金属中心离子与来自3个不同MOPIP分子上的6个氮原子进行配位,形成畸变的八面体构型。 |
| 关 键 词： | 2-(4-甲氧基)-1氢-咪唑[4，5-f][1，10]邻菲咯啉 锰(Ⅱ) 镉(Ⅱ) |
Synthesis, Characterization and Crystal Structure of Two Metal-Organic Complexes with MOPIP |
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| HUANG Yan-Ju,NI Liang,DU Gang,CUI Yun-Cheng,ZHANG Wen-Li,WANG Lei and HAO Xiang-Rong.Synthesis, Characterization and Crystal Structure of Two Metal-Organic Complexes with MOPIP[J].Chinese Journal of Inorganic Chemistry,2010,26(7):1269-1273. | |
| Authors: | HUANG Yan-Ju NI Liang DU Gang CUI Yun-Cheng ZHANG Wen-Li WANG Lei and HAO Xiang-Rong |
| Abstract: | Two unusual zero-dimensional (0D) compounds, viz. Cd(MOPIP)3(H2O)9]4n (1) and Mn(MOPIP)3(H2O)6]2n (2), are synthesized by the combination of two different metallic salts and 2-(4-methoxyphenyl)-1H-imidazo4,5-f]1,10] phenanthroline (MOPIP) ligand. The compounds have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The results show that every metal ion is hexa-coordinated with six nitrogen atoms from three different MOPIP ligands in the crystal structure, showing a slightly distorted octahedral geometry. CCDC: 775844, 1; 775845, 2. |
| Keywords: | 2-(4-methoxyphenyl)-1H-imidazo[4 5-f][1 10] phenanthroline |
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