| Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium（Ⅲ）-PYBOX Complex |
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| 引用本文： | 陆军,纪顺俊.Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium（Ⅲ）-PYBOX Complex[J].中国化学,2006,24(10):1439-1442. |
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| 作者姓名： | 陆军 纪顺俊 |
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| 作者单位： | Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry and Chemical Engineering of Suzhou University，Suzhou，Jiangsu 215123，China，Key Laboratory of Organic Synthesis of Jiangsu Province，College of Chemistry and Chemical Engineering of Suzhou University，Suzhou，Jiangsu 215123，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(No.20472062)，the Natural Science Foundation of Education Committee of Jiangsu Province(No.05KJB150116). |
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| 摘 要： | An indium complex of chiral pyridine bis(oxazoline)(PYBOX)has been applied to the catalytic asymmetricallylation of ketones.It has been found that this chiral indium complex is strong enough to promote the reaction ofketones with allyltributylstannane smoothly.The products were obtained in moderate yields with low to moderateenantioselectivities.
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| 关 键 词： | 铟配合物 催化剂 PYBOX 不对称烯丙基化 烯丙基三丁基锡烷 酮 |
| 收稿时间： | 2005-11-09 |
| 修稿时间： | 2005-11-092006-06-28 |
Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium(III)‐PYBOX Complex |
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| LU Jun, JI Shun-Jun.Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium(III)‐PYBOX Complex[J].Chinese Journal of Chemistry,2006,24(10):1439-1442. |
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| Authors: | LU Jun JI Shun-Jun |
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| Institution: | Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering of Suzhou University, Suzhou, Jiangsu 215123, China |
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| Abstract: | An indium complex of chiral pyridine bis(oxazoline)(PYBOX)has been applied to the catalytic asymmetric allylation of ketones.It has been found that this chiral indium complex is strong enough to promote the reaction of ketones with allyltributylstannane smoothly.The products were obtained in moderate yields with low to moderate enantioselectivities. |
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| Keywords: | indium PYBOX asymmetric allylation allyltributylstannane ketone |
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