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A Mössbauer effect study of the manganese-rich Y6(Fe1−xMnx)23 compounds
Authors:G.J. Long  K. Hardman  W.J. James
Affiliation:1. Department of Chemistry and the Graduate Center for Materials Research, Univesity of Missouri-Rolla, Rolla, MO 65401, U.S.A.;2. Nuclear Physics Division, Atomic Energy Research Establishment, Harwell, Didcot, Oxforshire OX11 ORA, England
Abstract:A Mössbauer effect spectral study of Y6[Fe0.1Mn0.9]23 and Y6[Fe0.2Mn0.8]23 indicated no internal hyperfine field and hence no spontaneous long-range magnetic ordering at temperatures from 300- 1.5 K. The same result was obtained at 4.2 K in applied magnetic fields of up to 6 T. The maximum possible spontaneous magnetic moment on the iron is less than 0.03 μβ. The absence of spontaneous ordering is a result of the disruption of manganese-manganese interactions by the iron.
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