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Jahn-Teller band transition in La3S4 and La3Se4
Authors:K. Westerholt  H. Bach  S. Methfessel
Affiliation:Institut für Experimentalphysik IV, Ruhr-Universität Bochum, D463 Bochum, West Germany
Abstract:La3S4 and La3Se4 undergo a cubic to tetragonal phase transformation at a temperature of 103 and 70 K respectively, the c/a ratio is 0.984 for La3S4 and 0.987 for La3Se4. In these compounds the conduction electron Fermi energy happens to be close to a band structure anomaly which drives the phase transition. We find some indication, that the anomaly might be of ?-type.
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