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Raman scattering in layered compound 2H-WS2
Authors:T Sekine  T Nakashizu  K Toyoda  K Uchinokura  E Matsuura
Institution:Institute of Physics, The University of Tsukuba, Sakura-mura, Ibaraki 305, Japan
Abstract:Raman scattering of layer-type compound 2H-WS2 has been studied at room temperature. The first-order Raman peaks are observed at 27.4, 357 and 423 cm-1. The low-frequency peak at 27.4 cm-1 is a rigid-layer mode, from which the interlayer shear force constant is estimated. The central force model is applied to the high-frequency phonons. The interlayer shear force constant is much smaller than the intralayer force constants. We also find several peaks due to the second-order processes.
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