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Wavefunction symmetries and binding energies in GaSxSe1?x compounds
Authors:G Margaritondo  AD Katnani  NG Stoffel  F Levy  I Abbati
Institution:Department of Physics, University of Wisconsin, Madison, WI 53706, U.S.A.;Laboratoire de Physique Appliquée de l''Ecole Polytechnique Federale, Lausanne, Switzerland;Istituto di Fisica, Politecnico di Milano, Italy
Abstract:We report on a synchrotron radiation photoemission spectroscopy study of mixed GaSxSe1?x crystals. The most prominent composition effect in the valence band is an increase by ~ 0.4 eV of the energy separation between the pz states and the px, py states as x increases from 0 to 1. The repulsion in energy is accompanied by a progressive mixing of these states in k-space regions far from the zone boundaries.
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