| 用奎宁拆分顺式菊酸 |
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| 引用本文： | 唐除痴,成俊然,李广仁,邵瑞链,金桂玉.用奎宁拆分顺式菊酸[J].高等学校化学学报,1988,9(11):1193. |
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| 作者姓名： | 唐除痴 成俊然 李广仁 邵瑞链 金桂玉 |
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| 作者单位： | 南开大学元素有机化学研究所 |
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| 摘 要： | 菊酸2,2-二甲基3-(2-甲基丙烯基)环丙烷羧酸]是除虫菊酯类杀虫剂的重要中间体。在其分子中,相对于环丙烷平面存在顺、反异构体。由于环上有两个毛性碳原子,因而有4个旋光异构体。
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| 关 键 词： | 顺式菊酸 奎宁 拆分 |
| 收稿时间： | 1987-06-02 |
Resolution of Cis-Chrysanthemic Acid With Quinine |
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| Tang Chuchi,Chen Junran,L.I Gungren,Shao Ruilian,Jin Guiyu.Resolution of Cis-Chrysanthemic Acid With Quinine[J].Chemical Research In Chinese Universities,1988,9(11):1193. |
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| Authors: | Tang Chuchi Chen Junran LI Gungren Shao Ruilian Jin Guiyu |
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| Institution: | Institute of Elemento-Organio Chemistry, Nankai University, Tianjin |
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| Abstract: | (±)-Cis-chrysanthemic acid 1 was resolved into (+)-1R-1 and(-)-1S-1 via the diastereomeric salts by using quinine as resolution reagent. Thus,the mixture of equimolar amount of (±)-1 and quinine was heated in EtOH-H2O(4:1 V/V) to have been solved cmpletely and was allowed to standundisturbed in a water bath at, 43~35℃ for 12~16h. The fine needles obtainedwere recrystallized. |
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| Keywords: | Cis-chrysanthemic acid Quinine Resolution |
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