| Synthesis and Structure of [HOCH2CH2N（CH3）3]4[Cu4OCl10] |
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| 引用本文： | 吴鼎铭,黄小荥,等.Synthesis and Structure of [HOCH2CH2N（CH3）3]4[Cu4OCl10][J].结构化学,1994,13(5):385-388. |
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| 作者姓名： | 吴鼎铭 黄小荥 等 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian，350002 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ［ＨＯＣＨ_２ＣＨ_２Ｎ（ＣＨ_３）_３］_４［Ｃｕ_４ＯＣｌ_（１０）］ＷｕＤｉｎｇ－Ｍｉｎｇ；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ；ＺｈｕａｎｇＨｏｎｇ－Ｈｕｉ（ＳｔａｔｅＫｅｙＬａｂｏｒａｔｏｒｙｏｆＳｔｒｕｃｔ?..
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| 关 键 词： | 合成 晶体结构 金属配合物 铜 三甲基羟基乙基铵盐 |
Synthesis and Structure of[HOCH_2CH_2N(CH_3)_3]_4[Cu_4OCl_(10)] |
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| Wu Ding-Ming,Huang Xiao-Ying,Zhuang Hong-Hui.Synthesis and Structure of[HOCH_2CH_2N(CH_3)_3]_4[Cu_4OCl_(10)][J].Chinese Journal of Structural Chemistry,1994,13(5):385-388. |
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| Authors: | Wu Ding-Ming Huang Xiao-Ying Zhuang Hong-Hui |
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| Institution: | [1]StateKeyLaboratoryofStructuralChemistry,FujianInst [2]StateKeyLaboratoryofStructura,FujianInst |
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| Abstract: | The title compound,C10H56Cl10Cu4N4O5,Mr=1041.40,has been prepared by reaction of CuCl and choline chloride in CH3CN.It crystallizes in the monoclinic system,space group C2/c with a= 22.55 (1),b=10.442(2),c=18.742(3),β=113.40(3)°,V=4050(3)3,Z=4,λ(MoKα)=0.71069,F(000)=2120,Dc=1.71 g/cm3 and μ(MoKα)=27.81 cm-1.The structure was solved by direct methods and refined by full-matrix least squares to final R and Rω values:0.070 and 0.076,respectively.The tetranuclear anion contains a central oxide ion coordinated tetrahedrally to four copper(Ⅱ) ions;the copper(Ⅱ) ions are bridged in pairs by six chloride ions.The remaining four chloride ions completed a trigonal-bipyramidal coordination sphere around each copper(Ⅱ) ion.There are two crystallographically independent and virtually identical cations in each asymmetrical unit. |
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| Keywords: | Cu_4] complex synthesis crystal structure |
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