| Synthesis,Structure and Property of a 1D Coordination Polymer [Mn{5-（NO2）sal}2（phen）]n with 5-Nitrosalicylate Ligand |
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| 引用本文： | 温德才,谢静,姜秀榕.Synthesis,Structure and Property of a 1D Coordination Polymer [Mn{5-（NO2）sal}2（phen）]n with 5-Nitrosalicylate Ligand[J].结构化学,2009,28(3):279-282. |
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| 作者姓名： | 温德才 谢静 姜秀榕 |
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| 作者单位： | Department of Chemistry, Longyan University, Longyan 364000, China
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| 基金项目： | supported by the Education Department of Fujian Province (No. JA02261) |
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| 摘 要： | A new coordination polymer Mn{5-（NO2）sal}2（phen）]n （5-（NO2）sal = 5-nitrosalicylate, phen = 1,10-phenanthroline） was synthesized by a hydrothermal reaction and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The title complex crystallizes in orthorhombic, space group Pbcn with α = 25.747（8）, b = 13.220（4）, c = 7.009（3） A, V= 2386（1）A^3, Z = 4, R = 0.0427 and wR = 0.0890. The 5-nitrosalicylate anions doubly bridge the Mn（Ⅱ） atoms to form a one-dimensional polymeric chain with repeated eight-membered ring units （Mn-O-C-O）2. The crystal structure is stabilized by intra- and interchain hydrogen bonding interactions. The cyclic voltammetric behavior of the title complex is also reported.
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| 关 键 词： | 配位聚合物 二氧化氮 phen 晶体结构 拉萨 一维 锰 合成 |
Synthesis,Structure and Property of a 1D Coordination Polymer [Mn{5-(NO_2)sal}2_(phen)]_n with 5-Nitrosalicylate Ligand |
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| WEN De-Cai,XIE Jing,JIANG Xiu-Rong.Synthesis,Structure and Property of a 1D Coordination Polymer [Mn{5-(NO_2)sal}2_(phen)]_n with 5-Nitrosalicylate Ligand[J].Chinese Journal of Structural Chemistry,2009,28(3):279-282. |
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| Authors: | WEN De-Cai XIE Jing JIANG Xiu-Rong |
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| Affiliation: | Department of Chemistry, Longyan University, Longyan 364000, China |
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| Abstract: | A new coordination polymer Mn{5-(NO2)sal}2(phen)]n (5-(NO2)sal = 5-nitrosa-licylate, phen = 1,10-phenanthroline) was synthesized by a hydrothermal reaction and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The title complex crystallizes in orthorhombic, space group Pbcn with a = 25.747(8), b = 13.220(4), c = 7.009(3) (A), V= 2386(1) A3,Z = 4, R = 0.0427 and wR = 0.0890. The 5-nitrosalicylate anions doubly bridge the Mn(Ⅱ) atoms to form a one-dimensional polymeric chain with repeated eight-membered ring units (Mn-O-C-O)2.The crystal structure is stabilized by intra- and interchain hydrogen bonding interactions. The cyclic voltammetric behavior of the title complex is also reported. |
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| Keywords: | coordination polymer 5-nitrosalieylic acid crystal structure |
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