Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units |
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| Authors: | Liu Cai-Ming Zhang De-Qing Zhu Dao-Ben |
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| Affiliation: | Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, CAS, Beijing, 100080, P. R. China. cmliu@iccas.ac.cn |
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| Abstract: | The non-uniform chain manganese(III) complex constructed from EE-azido bridged MnIII3O units, [MnIII3O(Brppz)3-(MeOH)3(N3)] 2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)-pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior. |
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