Vibrational modes of the stibine molecule |
| |
| Authors: | L. Pluchart N. Sanzharov F. Michelot O. Ulenikov |
| |
| Affiliation: | a Laboratoire de Physique de l’Université de Bourgogne—UMR CNRS 5027, B.P. 47 870, F-21078 Dijon Cedex, France
b Laboratory of Molecular Spectroscopy, Physics Department, Tomsk State University, Tomsk 634050, Russia |
| |
| Abstract: | In this paper, we use the algebraic approach to describe the vibrational modes of stibine molecule (of C3v molecular symmetry group) up to 21 quanta. As the stibine molecule exhibits stretch-bend resonances, we build an algebraic pyramidal coupling operator between stretching modes and bending modes adapted to this molecule. The standard deviation associated to the fit of the vibrational levels is 1.75 cm−1. |
| |
| Keywords: | Algebraic approach Vibrational modes High excited levels SbH3 molecule |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
