Excess molar volumes of (ethyl formate or ethyl acetate + an isomer of hexanol) at 298.15 K |
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| Authors: | J Ortega JS Matos MI Paz Andrade E Jimenez |
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| Institution: | Cátedra de Termodinámica y Fisicoquimica, Escuela Superior de Ingenieros Industriales, Las Palmas de Gran Canaria, Spain;Departamento de Fisica Fundamental, Facultad de Fisica, Universidad de Santiago, Santiago de Compostela, Spain |
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| Abstract: | Excess molar volumes VmE were determined over the entire composition range at 298.15 K for ethyl formate or ethyl acetate + hexan-1-ol, +2-methylpentan-1-ol, +3-methylpentan-2-ol, +2-methylpentan-3-ol, +3-methylpentan-3-ol, +2-methylpentan-2-ol, +4-methyl-pentan-2-ol, and +hexan-2-ol. Excess volumes were determined from density measurements made with a vibrating-tube densimeter. The VmE values were all positive, decreasing with the n value of the ester: Cn?1H2n?1CO2C2H5. |
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| Keywords: | To whom correspondence should be addressed |
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