Linear sweep voltammetry at the tubular graphite electrode: Part II. Totally irreversible processes |
| |
Authors: | Tejwant Singh Jatinder Dutt |
| |
Affiliation: | Water Resources Directorate (Pb.), Chandigarh India;Department of Chemical Engineering and Technology, Panjab University, Chandigarh India |
| |
Abstract: | The theory of linear sweep voltammetry at the tubular graphite electrode has been developed for irreversible processes. The convective diffusion differential equations have been transformed into an integral equation which is solved numerically. The current-potential curves have been calculated theoretically and verified experimentally. The dependence of the current-potential curves on velocity has been studied. A procedure for the determination of kinetic parameters, i.e. standard rate constant and transfer coefficient, is presented. |
| |
Keywords: | To whom correspondence should be addressed. |
本文献已被 ScienceDirect 等数据库收录! |