Synthesis of new siloxane or sulfur containing symmetrical monomers based on carvone |
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| Authors: | Fedor V. Drozdov Georgij V. Cherkaev Aziz M. Muzafarov |
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| Affiliation: | 1. Organosilicon Compounds Division, N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation;2. drozdov@ispm.ru;4. Organosilicon Compounds Division, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation |
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| Abstract: | AbstractWe demonstrated, that based on carvone, new symmetrical AA-type monomers with double bonds can be easily prepared by thiol-ene or Michael addition of dithiols. Moreover, hydrosilylation reaction with difunctional telehelic siloxane, containing Si-H groups was also studied. Obtained monomers are suitable for further polymerization by thiol-ene or hydrosilylation polyaddition. |
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| Keywords: | Carvone hydrosilylation thiol-ene click Michael addition |
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