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Reaction of germabenzenylpotassium with TBDMSCl: Unusual trimerization of germabenzene skeletons |
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| Authors: | Yoshiyuki Mizuhata Shiori Fujimori |
| Affiliation: | 1. Institute for Chemical Research, Kyoto University, Uji, Kyoto, Japan;2. Integrated Research Consortium on Chemical Sciences, Uji, Kyoto, Japan;3. tokitoh@boc.kuicr.kyoto-u.ac.jp;5. Catalysis Research Center and Institute of Silicon Chemistry, Technische Universit?t München, Garching bei München, Germany |
| Abstract: | AbstractThe reaction of 2-t-Bu-germabenzenylpotassium with Me2(t-Bu)SiCl (TBDMSCl) resulted in the coupling among two TBDMS-substituted germabenzenes and the germabenzenylpotassium. The structure of the product was determined by X-ray crystallographic analysis. Its formation mechanism was proposed with the help of theoretical calculations. |
| Keywords: | Germanium germabenzenyl anion germabenzene chlorosilane heavy phenyl anion |