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Accumulation of PCBs,PAHs, plasticizers and inorganic elements in Hexanchus griseus from the strait of Messina (Central Mediterranean sea)
Authors:Andrea Salvo  Archimede Rotondo  Valentina Mangano  Teresa Gervasi  Claudio Gervasi
Affiliation:1. Department of Biomedical and Dental Sciences and Morphofunctional Imaging, University of Messina (Italy), V.le Annunziata, Messina, 98168, Italy;2. Science4Life, Spin Off Company, University of Messina, V.le Leonardo Sciascia Coop Fede Pal. B, Messina, 98168, Italy;3. asalvo@unime.it
Abstract:Abstract

This study investigates the inorganic elements and the persistent organic pollutants (POPs) accumulated in liver of a sexually mature Hexanchus griseus living in the Mediterranean Sea. The casual finding of a specimen in the Strait of Messina (April 2018) allowed us to carefully analyse its liver which can be considered a very important biological indicator. The determination of inorganic elements was carried out by ICP-MS technique. Quantitative determination of polycyclic aromatic hydrocarbons (PAH) and poly-chloro-biphenyl compounds (PCB), distinguished in dioxine-like (DL) and not-dioxine-like (NDL) derivates, has been carried out by HRGC/MS and HRGC-MS/MS respectively. Worrying levels of PCB-DL (TEQ?=?Σ(PCB-DL)*TEF?=?5.96?ng g?1), PCB-NDL (Σ(PCB-NDL)?=?1390.4?ng g?1) together with the presence of pesticides and plasticizers were found in the shark liver oil. The levels of heavy metals were below the legal limits.
Keywords:Shark  Hexanchus griseus  heavy metals  PAHs  PCBs  Mediterranean Sea
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