Synthesis,characterization, and photophysical properties of paraben substituted cyclotriphosphazenes with hydrophilic side groups |
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Authors: | Elif ?enkuytu Hande Eserci Nagihan Bay?k Nadide Akba? Elif Okutan Gönül Yenilmez Çiftçi |
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Institution: | 1. Department of Chemistry, Faculty of Science, Gebze Technical University, Gebze, Kocaeli, Turkeysenkuytu@gtu.edu.tr;3. Department of Chemistry, Faculty of Science, Gebze Technical University, Gebze, Kocaeli, Turkey |
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Abstract: | AbstractIn this study, five new paraben substituted cyclotriphosphazene compounds containing hydrophilic glycol groups were successfully synthesized. All synthesized cyclotriphosphazene compounds 1-10 were fully characterized via general spectroscopic techniques such as 1H, 31P NMR and MALDI-TOF mass spectrometry. In addition, the investigations of the UV-vis absorption and fluorescence emission properties of the 1-10 carried out via absorption and fluorescence spectroscopies in different solvents. The absorbance bands of the all synthesized compounds 1-10 were observed at about 230–300?nm in all solvents studied. Furthermore, the highest fluorescence emission intensity of the compounds 1-10 was observed in tetrahydrofuran at about 312?nm and the lowest emission intensity was observed in chloroform. The synthesized molecules can be used as custom designed molecules to investigate the DNA binding properties in automatic biosensor device in our laboratories, since they carry hydrophilic glycol units for water solubility and paraben derivatives for DNA effecting properties. |
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Keywords: | Paraben cyclotriphosphazene hydrophilic tails UV-vis absorption fluorescence |
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