Isomeric ammonio derivatives of nido-carborane 3- and 10-H3N-7,8-C2B9H11 |
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Authors: | Sergey A. Anufriev Akim V. Shmal’ko Kyrill Yu. Suponitsky Igor B. Sivaev |
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Affiliation: | A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia |
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Abstract: | AbstractStructure of 3-ammonio derivative of nido-carborane 3-NH3-7,8-C2B9H11 was determined by single crystal X-ray diffraction. The isomeric 10-ammonio derivative 10-NH3-7,8-C2B9H11 was prepared by the treatment of the corresponding ethylnitrilium derivative 10-EtC≡N-7,8-C2B9H11 with hydrazine hydrate in acetonitrile. |
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Keywords: | Nido-carboranes ammonio derivatives synthesis X-ray structure |
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