Isostructural triazenido complexes of first row transition metals. Part 1. Synthesis and properties of (η5-C5H5)(L)(RN3R) FeII,L = PPh3, P(OMe)3, P(OPh)3 or CO期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

Isostructural triazenido complexes of first row transition metals. Part 1. Synthesis and properties of (η5-C5H5)(L)(RN3R) FeII,L = PPh3, P(OMe)3, P(OPh)3 or CO

Authors:	Ernst Pfeiffer Kees Vrieze

Institution:	(1) Anorganisch Chemisch Laboratorium, J. H. van't Hoff Instituut, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands

Abstract:	Summary The complexes ( ⁵-C₅H₅)L(RN₃R)Fe, where L = PPh₃, P(OMe)₃, P(OPh)₃ or CO and R,R=p-MeC₆H₄ orp-ClC₆H₄, have been prepared by reaction of suitable iron halides with Ag(RN₃R). The mechanism of formation of the Fe(RN₃R) group is thought to involve, initially, an Fe-Ag bond. The bonding mode of the triazenido ligand is chelating in a six coordinate configuration. The spectroscopic results are discussed in relation to variations in the environment of the metal atom.

Keywords:
本文献已被 SpringerLink 等数据库收录！