Thallium trinitrate mediated oxidation of 3-alkenols: ring contraction vs cyclization |
| |
Authors: | Ferraz Helena M C Longo Jr Luiz S Zukerman-Schpector Julio |
| |
Institution: | Departamento de Química, Universidade Federal de S?o Carlos, CEP 13565-905, S?o Carlos SP, Brazil. hmferraz@iq.usp.br |
| |
Abstract: | The reaction of a series of six-membered ring 3-alkenols with thallium trinitrate (TTN) in three different experimental conditions was studied. Either cyclization products or ring contraction products were obtained, depending on the structure of the substrate as well as the nature of the solvent. The reaction of a seven-membered ring 3-alkenol with TTN led to the ring contraction product exclusively. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|