Optical and luminescent VUV spectroscopy of La2Be2O5 crystals

Electronic excitations and the processes of their radiative relaxation are studied in pure and Ce³⁺ ion-doped crystals of lanthanum beryllate excited by synchrotron radiation in the x-ray and VUV ranges by methods of optical and luminescent vacuum ultraviolet time-resolved spectroscopy. Manifestations of excitons of the valence band are absent in the reflection spectra. However, a fast (τ=1.7 ns) and a slow (microsecond range) channel corresponding to two possible types of self-trapped excitons (STE) are found in radiative relaxation of intrinsic electronic excitations at T=10 K. The slow channel corresponds to emission of STE formed through recombination, the fast channel corresponds to emission of relaxed metastable excitons from the STE state. In the energy region higher than 14 eV (E>2E _g), the effect of multiplication of electronic excitations due to generation of secondary electron-hole pairs resulting from inelastic scattering of both hot photoelectrons and hot photoholes is exhibited.