| 牛磺酸缩3，5-二溴水杨醛席夫碱镁配合物[Mg(Br2TSSB)(Phen)(H2O)]·H2O的合成及晶体结构 |
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| 引用本文： | 辛懋,张淑华,杜荣斌,蒋毅民,孙伟娜,廖松明. 牛磺酸缩3，5-二溴水杨醛席夫碱镁配合物[Mg(Br2TSSB)(Phen)(H2O)]·H2O的合成及晶体结构[J]. 无机化学学报, 2006, 22(1): 179-182 |
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| 作者姓名： | 辛懋 张淑华 杜荣斌 蒋毅民 孙伟娜 廖松明 |
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| 作者单位： | 1. 广西师范大学化学化工学院,桂林,541004
2. 桂林工学院材料与化学工程系,桂林,541004 |
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| 基金项目： | 广西自然科学基金;广西教育厅科研项目 |
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| 摘 要： | Reactions of bitter salt with taurine-3,5-dibromo-salicylaldehyde schiff base gave one new Complex [Mg(Br2TSSB)(Phen)(H2O)]·H2O (Br2TSSB=Taurine 3,5-dibromo-Salicylaldehyde Schiff Base, phen=o-phenanthroline), which was characterized by elemental analysis, IR and X-ray diffraction. The chemical formula weight of the complex is 625.58. It′s crystal belongs to monoclinic system with space group P21/c. The cell parameters are: a=1.814 2(3) nm, b=0.814 75(14) nm, c=1.641 7(3) nm, β=90.571(4)°, and Z=4, V=2.426 4(7) nm3, Dc=1.712 g·cm-3, F(000)=1 248, μ=3.496 mm-1. The complexes form a 3D net structure in which they are connected with hydrogen bonds and π-π stacking. The Mg(II) formed a distorted coordination tetragonal pyramid. CCDC: 286194.
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| 关 键 词： | 牛磺酸缩3，5-二溴水杨醛席夫碱； 晶体结构； 镁配合物 |
| 文章编号： | 1001-4861(2006)01-0179-04 |
| 收稿时间： | 2005-07-08 |
| 修稿时间： | 2005-10-27 |
Synthesis and Structure of Magnesium Complex [Mg(Br2TSSB)(Phen)(H2O)]·H2O |
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| XING Mao,ZHANG Shu-Hu,DU Rong-Bin,JIANG Yi-Min,SUN Wei-Na and LIAO Song-Min. Synthesis and Structure of Magnesium Complex [Mg(Br2TSSB)(Phen)(H2O)]·H2O[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(1): 179-182 |
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| Authors: | XING Mao ZHANG Shu-Hu DU Rong-Bin JIANG Yi-Min SUN Wei-Na LIAO Song-Min |
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| Affiliation: | Department of Chemistry, Guangxi Normal University, Guilin, Guangxi 541004,Department of Material and Chemical Engineering, Guilin University of Technology, Guilin, Guangxi 541004,Department of Material and Chemical Engineering, Guilin University of Technology, Guilin, Guangxi 541004,Department of Chemistry, Guangxi Normal University, Guilin, Guangxi 541004,Department of Material and Chemical Engineering, Guilin University of Technology, Guilin, Guangxi 541004 and Department of Material and Chemical Engineering, Guilin University of Technology, Guilin, Guangxi 541004 |
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| Abstract: | |
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| Keywords: | taurine 3,5-dibromo-salicylaldehyde Schiff base crystal structure magnesium complex |
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