| 温度诱导双水相体系中扁桃酸的手性识别研究 |
| |
| 引用本文： | 邢健敏,李芬芳.温度诱导双水相体系中扁桃酸的手性识别研究[J].高等学校化学学报,2009,30(9):1744-1747. |
| |
| 作者姓名： | 邢健敏 李芬芳 |
| |
| 作者单位： | 中南大学化学化工学院,长沙,410083 |
| |
| 基金项目： | 湖南省自然科学重点基金(批准号:08jj3023);;中南大学优秀博士学位论文(批准号:2008yb036)资助 |
| |
| 摘 要： | 以双水相体系为手性识别体系, 研究了异丙醇/盐和TritonX-114温度双水相体系中扁桃酸的分配行为. 对于醇/盐体系, 扁桃酸均倾向于分配在醇相中, 不适合作为手性识别系统; 而对于TritonX-114温度双水相体系, 扁桃酸富集于水相, 适合作为手性识别系统. 以L-酒石酸正戊酯和β-环糊精作为手性识别剂, 对TritonX-114/L-酒石酸正戊酯、TritonX-114/L-酒石酸正戊酯/茶皂素和TritonX-114/β-环糊精3个识别体系的研究发现, TritonX-114/L-酒石酸正戊酯/茶皂素和TritonX-114/β-环糊精体系中, 手性识别效果明显, 最佳分离体系为: 茶皂素含量0.51 mmol, L-酒石酸正戊酯含量1.4 mmol, 温度55 ℃, 最大分离因子1.29.
|
| 关 键 词： | 双水相体系 手性识别 温度诱导 |
| 收稿时间： | 2009-01-12 |
Induced Double Aqueous Phases System |
| |
| XING Jian-Min,LI Fen-Fang.Induced Double Aqueous Phases System[J].Chemical Research In Chinese Universities,2009,30(9):1744-1747. |
| |
| Authors: | XING Jian-Min LI Fen-Fang |
| |
| Institution: | School of Chemistry and Chemical Engineering;Central South University;Changsha 410083;China |
| |
| Abstract: | The partitioning behavior of mandelic acid was studied on the isopropyl alcohol/salt and TritonX-114 temperature induced system.The results show that the mandelic acid tends to exist in the isopropyl alcohol phase of the isopropyl alcohol/salt system,and in the water phase of the TritonX-114 temperature induced system,so the TritonX-114 temperature induced system was used as chiral recognition system.The chiral recognition of mandelic acid was investigated in the TritonX-114/n-amyl-L-tartrate/teasaponin and... |
| |
| Keywords: | Double aqueous phases system Chiral recognition Temperature induced |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
