Photocycloaddition of biscyclopropyl alkenes to C60: an unprecedented approach toward cis-1 tricyclic-fused fullerenes |
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| Authors: | Tzirakis Manolis D Alberti Mariza N Orfanopoulos Michael |
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| Institution: | Department of Chemistry, University of Crete, GR 71003, Heraklion, Greece. |
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| Abstract: | A novel, simple, and entirely regioselective tandem cycloaddition of biscyclopropyl-substituted alkenes to 60]fullerene has been revealed. This reaction affords cis-1 tricyclic-fused organofullerenes bearing the hitherto elusive 5-4-5 fused tricyclic ring system. |
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