Stereoselective gamma-lactam synthesis via palladium-catalysed intramolecular allylation |
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| Authors: | Craig Donald Hyland Christopher J T Ward Simon E |
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| Institution: | Department of Chemistry, Imperial College London, South Kensington Campus, London, UK SW7 2AZ. d.craig@imperial.ac.uk |
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| Abstract: | A novel route to the synthesis of 3-(tolylsulfonyl)-4,5-cis-disubstituted gamma-lactams using a diastereoselective palladium-catalysed intramolecular allylation of amino acid-derived allylic carbonates has been developed. |
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