A mild thermal and acid-catalyzed rearrangement of O-aryl ethers into ortho-hydroxy arenes |
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| Authors: | Goldberg Frederick W Magnus Philip Turnbull Rachel |
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| Institution: | Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, USA. |
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| Abstract: | reaction: see text] An unusual rearrangement of an O-aryl ether to an ortho-hydroxyaryl system was discovered during our studies on the synthesis of diazonamide A. We discuss the exploration of this rearrangement under mild thermal and both Br?nsted and Lewis acid-catalyzed conditions. |
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