Die Störung durch kleine Wassergehalte bei der Messung der Dissoziationsenthalpie von Ga2Cl6 = 2 GaCl3 |
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Authors: | Harald Sch fer,Rudolf Becker-Kaiser |
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Affiliation: | Harald Schäfer,Rudolf Becker-Kaiser |
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Abstract: | Disturbance by Small Water Contents during the Measurement of the Dissociation Enthalpy of Ga2Cl6 = 2 GaCl3 Small water contents are difficult to exclude before the dissociation of Ga2Cl6 is studied. Taking into account the small amount of HCl, which arises from that, the values ΔH°(298) = 22.49 kcal and ΔS°(298) = 35.95 cal/K are obtained using ΔCp = ?4 cal/K we got for Ga2Cl6,g = 2 GaCl3,g. |
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