Cobalt(III)-Gemischtligandenkomplexe mit Phenanthrolin und Picolinsäure. Darstellung,Charakterisierung und einige photochemische Eigenschaften |
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| Authors: | V I Pawlowski A L Poznjak |
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| Abstract: | Mixed-Ligand Complexes of Cobalt(III) with Phenanthroline and Picolinate. Preparation, Characterization, and Some Photochemical Properties Three new cobalt(III) complexes, Co(phen)2pic2+, trans(N)? Co(pic)2phen+, and trans(O)? Co(pic)2phen+ (phen-1, 10-phenanthroline, pic-picolinate), have been isolated and characterized by 1H-NMR and UV-VIS spectra. Some preliminary data concerning biacetyl-sensitized photochemical decomposition of these complexes in aqueous solutions are reported. |
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