Abstract: | Isolated Square-Planar Coordinated Pt2+ Inside of BaNd2PtO5 Single crystals of the hitherto unknown compound BaNd2PtO5 were prepared and examined by X-ray technique. The compound crystallizes with tetragonal symmetry D ? P4 b2; a = 6.7569(6) and c = 5.9119(13) Å; Z = 2. The structure is discussed in respect of the isolated square-planare coordination of Pt2+ ions and its relation with other planar coordinated platinum of oxocompounds. |