Beiträge zur Chemie der Silicium-Schwefel-Verbindungen. XXXVI [1]. Das Quecksilber(II)-bis-tri-tert-butoxysilanthiolat |
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| Authors: | Wies&#x;aw Wojnowski Maria Wojnowski Hans Georg von Schnering Mathias Noltemeyer |
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| Institution: | Wiesław Wojnowski,Maria Wojnowski,Hans Georg von Schnering,Mathias Noltemeyer |
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| Abstract: | Contributions to the Chemistry of Silicon-Sulfur Compounds. XXXVI. Mercury(II)-bis-tri-tert-butoxysilanethiolate Mercury(II)bis-tri-tert-butoxysilanethiolate was obtained in reaction of HgO with (t-C4H9O)3SiSH. This compound forms colourless triclinic plates. The central S? Hg? S bond element is linear, with Hg? S bond distance of 231.6 pm. The Hg atom is coordinated by two oxygens of the two butoxy groups, with Hg? O distance of 287.8 pm. The mean bond angle at the two-bonded sulfur is 95.6°. (Space group P1 ; a = 930.8, b = 944.0, c = 1204.8 pm, α = 100.34, β = 97,64, γ = 116.50°; Z = 1; R = 0.035; 3390 reflections hkl). |
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