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Cationic Ruthenium(II) Carbonyl Complexes with Nitrile Ligands |
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| Authors: | Sarada Gopinathan S S Deshpande C Gopinathan |
| Abstract: | Stable cationic complexes of the type RuCO(PPh3)2(L)(RCN)]+ClO4]? derived from acetonitrile and acrylonitrile have been synthesized. The bidentate ligands (LH) used are acetylacetone, benzoylacetone, dibenzoylmethane, trifluorothenoyl acetone and 8-hydroxyquinoline. The complexes have been characterized by elemental analysis, IR, conductivity, 1H and 31P NMR and ESCA studies, and possible stereochemistry has been established. |
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