Die Bildung von CoAl3Cl11 bei größeren Al2Cl6-Drücken |
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Authors: | Harald Sch fer,Rudolf Becker-Kaiser |
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Affiliation: | Harald Schäfer,Rudolf Becker-Kaiser |
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Abstract: | Formation of CoAl3Cl11 at higher Al2Cl6 Pressures The reaction of CoCl2,f with Al2Cl6,g (≈ 3 atm) is investigated considering every component of the gas phase (Al2Cl6, AlCl3, Al3Cl9, CoAlCl5, CoAl2Cl8, CoAl3Cl11) and the deviation from the ideal behaviour. The conclusion is derived that at 600 K from CoCl2,s and larger pressures of Al2Cl6 besides CoAl2Cl8 a small amount of CoAl3Cl11 is formed. |
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