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Studies on comblike polymers. X. Characterization of comblike polyesters by 13C NMR spectroscopy
Authors:Anna Laura Segre  Fulvio Andruzzi  Corrado Barone  Massimo Paci  Pier Luigi Magagnini
Abstract:The 13C NMR spectra of aromatic comblike polyesters obtained from 1,2-icosanediol and isomeric phthalic acids are reported and discussed. The analysis shows that the most informative spectral regions are those of the carbonyl and quaternary carbon resonances, whose peak multiplicities have been interpreted in terms of dyad and triad sequences. The results indicate that the extent of structural characterization possible for the polymers examined is dependent on the type of isomerism of the aromatic acid involved.
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