Nanocrystalline nature of high-symmetry Ce4+-Eu3+ centers in silica gel glasses

The spectral-luminescent properties of silica gel glasses coactivated by Ce⁴⁺ and Eu³⁺ ions are investigated. The structure of the glasses is studied using x-ray powder diffraction and small-angle neutron scattering. The inference is drawn that Ce⁴⁺-Eu³⁺ centers with high-symmetry Eu(III) oxo complexes, which are formed in the glasses, have nanocrystalline nature. These centers are characterized by a weak vibronic interaction of Eu³⁺ ions with the matrix. The size of nanocrystallites formed under the synthesis conditions and at coactivator concentrations used is approximately equal to 10 nm.