A lvt‐type Framework [Cu2(tza)4]·ClO4·4H2O Derived from 1H‐tetrazole‐1‐acetic Acid |
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| Authors: | Li Ma Guo Peng Jin‐Biao Cai Dr. Hong Deng Matthias Zeller |
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| Affiliation: | 1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006 P. R. China;2. Key Lab of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510631, P. R. China;3. Department of Chemistry, Youngstown State University, One University Plaza, Youngstown Ohio 44555–3663, USA |
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| Abstract: | The reaction of 1H‐tetrazole‐1‐acetic acid (Htza) and perchloric acid with cuprous chloride with slow evaporation at room temperature gave a novel 3D porous CuII coordination polymer, [Cu2(tza)4] · ClO4 · 4H2O ( 1 ), (tza = tetrazole‐1‐acetate). The structure exhibits an unusual 3D microporous coordination framework built up by four coordinated CuII nodes and bidentate bridging tza ligands with lvt‐type topology. Furthermore, the magnetic properties of complex 1 were also investigated. |
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| Keywords: | 1H‐tetrazole‐1‐acetic acid Magnetic properties lvt Topology Porous Coordination polymer |
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