Synthesis,Crystal Structure,and Properties of the 3D Porous Framework [Zn(INAIP)]·DMA·H2O |
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| Authors: | Dr Man‐Sheng Chen Xiong‐Wen Tan Dr Chun‐Hua Zhang Dai‐Zhi Kuang |
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| Institution: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China |
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| Abstract: | A new three‐dimensional (3D) porous framework Zn(INAIP)] · DMA · H2O ( 1 ) INAIP = 5‐(isonicotinamido)isophthalate, DMA = N,N′‐dimethylacetamide] was synthesized by solvothermal methods and characterized by single‐crystal and powder X‐ray diffraction, as well as thermogravimetric analysis. The results of X‐ray diffraction analyses revealed that complex 1 has an unusual 3D architecture with the (3,6)‐connected rutile ( rtl ) topology. The adsorption behavior shows that compound 1 exhibits selective adsorptions of CO2 over N2 after the removal of the solvent molecules within the pores. |
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| Keywords: | Zinc Solvothermal reactions Porous frameworks Sorption behavior Metal‐organic frameworks |
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