Surface and electrochemical analysis for the understanding of TiO2 nanopores/nanotubes changes in post‐elaboration treatment |
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Authors: | Claudiu Constantin Manole Cristian Pirvu |
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Affiliation: | Faculty of Applied Chemistry and Materials Science, University Politehnica Bucharest, Str. Polizu 1‐7, 011061, Sector 6, Bucharest, Romania |
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Abstract: | The electrochemical stability of TiO2 nanoarchitecture fabricated in fluoride electrolyte presented in this paper is related to 2D and 3D geometries that present a shift from nanopores toward nanotubes. The fabrication conditions involve a 60 V applied voltage for 2 hours of anodizing in order to create the ordered structures, in a mixture of low‐water glycerol electrolyte and fluoride. With the use of different ultrasonication times, a variety of nanotubes/nanopores were observed. The surface interfacial aspects were investigated mainly by surface microscopy and hydrophilic/hydrophobic balance for the grown structures ultrasonicated at various periods of time. The electrochemical behavior of the nanotube‐structured surface was performed by potentiodynamic evaluation and electrochemical impedance spectroscopy in a simulated body fluid solution. As a most important result, all surface analysis and electrochemical data interpretation permitted the proposition of a model for elaboration of different nanostructures from nanopores to nanotubes. These different surface nanoarchitectures were obtained as a result of ultrasonication at various periods of time. Copyright © 2010 John Wiley & Sons, Ltd. |
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Keywords: | TiO2 ultrasonication electrochemical techniques atomic force microscopy (AFM) scanning electron microscopy (SEM) |
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