Syntheses,Crystal Structures,and Luminescence Properties of Dinuclear Metal (Ag+ and Cu+) Complexes with the Ligand 2‐MTPP [2‐MTPP = 2‐(Methylthio)‐4‐(pyridin‐2‐yl)pyrimidine] |
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| Authors: | Prof. Dr. Hai‐Bin Zhu Shu‐Ying Zhang Xin Lu Wen‐Na Yang Prof. Dr. Shao‐Hua Gou Jing Chen |
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| Affiliation: | 1. Pharmaceutical Research Center and, School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, P. R. China;2. Jiangsu Province Hi‐Tech, Key Laboratory for Bio‐Medical Research, Nanjing, 211189, P. R. China |
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| Abstract: | Reactions of the ligand 2 ‐ MTPP [2‐MTPP = 2‐(methylthio)‐4‐(pyridin‐2‐yl)pyrimidine] with AgNO3 and CuI produced dinuclear silver(I) ( 1 ) and copper(I) ( 2 ) complexes, respectively. Both complexes adopt a chair‐like structure in which two 2 ‐ MTPP ligands and two metal ions are joined together through M–N and M–S coordination bonds. The luminescence properties of both complexes were investigated in solid state at room temperature. |
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| Keywords: | Thioethers Copper Silver Crystal structure Luminescence |
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