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Synthesis, crystal structure, and luminescence properties of coordination polymers based on cadmium isonicotinates
Authors:M S Zavakhina  D G Samsonenko  M P Yutkin  D N Dybtsev  V P Fedin
Institution:19582. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
29582. Novosibirsk National Research University, Novosibirsk, Russia
39582. Division of the Advanced Materials Science, POSTECH, San 31, Hyojadong, Pohang, 790784, Republic of Korea
Abstract:Heating a solution of cadmium nitrate and isonicotinic acid in N,N′-dimethylformamide or dimethyl sulfoxide gave three new coordination polymers, Cd(Inic)2] · 0.5DMF (I), Cd3(DMSO)6(Inic)2(SO4)2] (II), and {Cd(DMSO)(Inic)}2(SO4)] · 2H2O (III), which were studied by X-ray crystallography. Compounds I and III were characterized by IR spectroscopy and elemental and thermogravimetric analyses and luminescence spectroscopy.
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