卟啉及其衍生物合成进展

按卟啉母核的不同合成方法，介绍了卟啉衍生物的合成进展。从各种小分子的缩合而合成卟啉的方法包括经典的Alder-Long法、Lindsey法和新颖的2＋2]法、3＋1]法。这些方法能够合成许多结构复杂的卟啉。对卟啉大分子进行β-、meso-位功能团的引入，有卤代、硝化、甲酰化等，并能进一步转化成其它功能团。

Advances in the Syntheses of Porphyrins and their Derivatives

Two strategies of construct porphyrin macrocycles are presented. Synthesis of porphyrins from condensation of pyrrole and aldehyde are realized by traditional Alder-Long method, Lindsey method and novel 2+2], 3+1] methods. It is a second policy to introduce functions into porphyrins, i. e. formylation, halogenation and nitration, or to perform interconversions of functional groups through coupling.