Functionalized pyrroles from vinylaziridines and alkynes via rhodium-catalyzed domino ring-opening cyclization followed by C C bond migration |
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| Authors: | Shu-Hao Wan Shiuh-Tzung Liu |
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| Institution: | Department of Chemistry, National Taiwan University, Taipei, 106, Taiwan |
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| Abstract: | Rhodium(I)-catalyzed intermolecular cycloadditions of alkynes with vinyl aziridines bearing a conjugated carbonyl group in the olefin moiety followed by the double migration resulted in the formation of pyrrole derivatives in a one pot fashion. |
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| Keywords: | Cycloaddition Aziridine Pyrrole Isomerization Rhodium |
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